The best way to go about it is to dive into the site from your mobile (www.whatsapp.com).

When you hit download, an .apk file will be downloaded (the version you need is2.11.552or above).

Now you make a call to that same user who called you to confirm your WhatsApp Calling is working.

WhatsApp calling comes to Android 4.0.0 and above, iOS and BlackBerry still in queue

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source: www.techworm.net